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Kuldeep Singh


ksblogs@gmail.com

Journal articles

2011
2010
2007
S Kotha, K Singh (2007)  Cross-enyne and ring-closing metathesis cascade : A building-block approach suitable for diversity-oriented synthesis of densely functionalized macroheterocycles with amino acid scaffolds   European Journal of Organic Chemistry 35. 5909-5916  
Abstract: Suitably functionalized glycine derivatives undergo a cross-enyne and ring-closing metathesis cascade to generate macroheterocyclic ring systems in good yield. These macrocycles, prepared on the basis of a fragment coupling strategy, consist of 13-16-membered rings. To this end, 1,5-hexadiene was found to be a promising cross-coupling partner to generate macrocycles by this tandem metathesis sequence. © Wiley-VCH Verlag GmbH & Co. KGaA, 2007.
Notes: Export Date: 23 July 2008
2004
P K Thallapally, R K R Jetti, A K Katz, H L Carrell, K Singh, K Lahiri, S Kotha, R Boese, G R Desiraju (2004)  Polymorphism of 1,3,5-trinitrobenzene induced by a trisindane additive   Angewandte Chemie - International Edition 43: 9. 1149-1155  
Abstract: The most stable is not necessarily the most easy to obtain! Two new stable crystal forms of the 120 year old compound sym-trinitrobenzene are reported. These elusive forms have been obtained by the use of an additive, trisindane, that can act as a mimic in the crystallization experiment (see scheme).
Notes: Cited By (since 1996): 32
S Kotha, K Singh (2004)  N-Alkylation of diethyl acetamidomalonate : Synthesis of constrained amino acid derivatives by ring-closing metathesis   Tetrahedron Letters 45: 52. 9607-9610  
Abstract: An efficient method for N-alkylation of diethyl acetamidomalonate (DEAM) is reported. C-Alkenylation was achieved by treating the N-alkenylated DEAM with various electrophiles in the presence of Cs2CO3. RCM reactions of C- and N-alkenylated products gave cyclic amino acid derivatives in good yields. An efficient method for N-alkylation of diethyl acetamidomalonate (DEAM) is reported. C-Alkenylation was achieved by treating the N-alkenylated DEAM with various electrophiles in the presence of Cs2CO3. RCM reactions of C- and N-alkenylated products gave cyclic amino acid derivatives in good yields. © 2004 Published by Elsevier Ltd.
Notes: Cited By (since 1996): 7
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